You are going from the biggest on the front to the biggest on the back, or the smallest on the front to the smallest on the back. This puts the chain on a diagonal running through the derailleurs. which is very stressful to your whole drivetrain. To avoid doing it, pay attention to where you chain is. If you are on the smallest in the front, when the chain on the back gets towards the middle of the cassette, move it to a bigger ring in the front to keep the chain as straight as possible. If you are using the gears on the smaller part of the cassette[IMG], keep the chain on the middle or biggest in the front.
Image of the diagonal
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