What do you mean by "jumping"? Do you mean the chain feels like it's skipping on top of the cog or is the chain trying to jump between cogs and not settling on any one cog?
The first is "skipping," and the second is "autoshifting."
Skipping: http://sheldonbrown.com/derailer-adj....html#skipping
Autoshifting: http://www.sheldonbrown.com/autoshift.html
Alternatively, your indexing may be off. Does it happen such that you have a hard time shifting up or down into that problem cog? If so, then it's an indexing issue. If you can shift fine but then it starts acting up under load, then it may be one of the other problems.
If indexing improves things some but not enough or not for long, then check the condition of your cables. Any obvious damage to the cable or housing? Is it really dry under your bottom bracket? Try lubing the cables under the BB. If nothing works and you're certain it is not a chain wear problem, then you might need to replace your cables. Since you had some issues recently with the FD as well that sounds like a cable tension problem, my guess is that your cables are just getting too old and need to be replaced. That's not surprising at the year mark with the mileage you've got. DA cables might last a bit longer (because they're thicker) but it's probably a good time to change them, particularly if they are not Dura Ace cables.