My riding pattern (on cleats or on platforms) uses a lot of butt. So I've got this rather ummm "rounded" posterior when viewed from the side. Buns of Steel! (and I've got wide hips, so I'm just looooooovely to behold, I'm sure...
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I seem to kick in more butt when I concentrate on good posture and keeping my lower abs firm.
Remember, the quads are a two-joint muscle complex. Part of them is also a hip FLEXOR. (brings your knee to your chest) So you've got to be kicking in a hip EXTENSOR to counterract that as you push down on the pedal. Your butt and hams are the biggies there. (but hams are a 2 joint complex, too.... so someone's gotta be counterracting the knee flexion activity if you are trying to use the ham as a hip extender as you push on the pedal) (quad and ham can get a good tug-o-war going!)
Butt: hip extensor
Quad: hip flexor, knee extensor
Ham: hip extensor, knee flexor
Upshot is, if you are pedalling you are automatically using your butt at least some and if you can concentrate on the muscles a little you can raise it's activity.
It's all about the co-contractions...
"If Americans want to live the American Dream, they should go to Denmark." - Richard Wilkinson