I will be very interested to see what you like out there. Good thread.
I haven't done much yet with podcasts, but along those lines, I REALLY like a cycling CD I bought and loaded onto my iPod. It is the Zooming CD from Ian Jackson. I ordered the set, which also has audio for both walking and running programs. I use the Zooming workout the most (it is specifically for cycling).
http://www.breathplay.com/



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). Anyhoo, when I got my ipod, I started downloading old movies and radio shows and they worked great! I've listened to tons of old radio plays and shows like Father Knows Best etc. I usually only hear the first 5-10 minutes before I fall asleep so sometimes on Saturday or Sunday mornings, I find one I've haven't heard the end of and I fast forward. 