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I forget the brand, but I have a padded pair of underwear that I got years ago from REI. It isn't the one linked above. I wear them sometimes to spin class. I've never had a problem with chafing. I think for a ride less than an hour, which I guess most commutes are, they would be fine, if you need padding for a ride that short. As long as the chamois is removable for the day, or you bring an extra pair of undies anyway, they should be fine. They certainly are more attractive than the pair I have, or any of my underwear, for that matter!
Grits
2010 Trek 5.2 Madone WSD, SI Diva Gel Flow
2002 Terry Classic, Terry Liberator