Yep, the PI Calientoes stay on great and do help. I tend to run quite cold, though, so I often wear wool socks, shoes, calientoes, and full neoprene shoe covers.
Honestly, I've wondered if I should get some neoprene shoe covers that have wind-proof outers, too. Did I mention I run cold?
One thing I like about the full covers is that where I live, winter means wet and sand. The shoe covers will get thoroughly gross from all the dirt and much and water on the road, but I can just toss them in the wash, and the shoes don't get soaked and filthy.
"The best rides are the ones where you bite off much more than you can chew, and live through it." ~ Doug Bradbury