He's already doing the most important thing - actually talking to the women. I'll bet a lot of women are basically ignored in LBSs until they walk up to a cash register with item in hand.
Also, sponsoring a Women's Clinic would be a good idea. The LBS here did that last year and it was a HUGH success. They expected about 40 people and ended up with about 200. It was a mtn. bike clinic. They had you rotate through stations. There were bike handling skills, ie. learning how to bunny hop over logs, maintenance skills, etc. Even had a pro racer at the clinic who gave a talked to us and did trail rides with us. It was very cool. They are doing it again this year.
As we must account for every idle word, so must we account for every idle silence." ~Benjamin Franklin