I have a Silque with 165 cranks. I do not have Di2, but the LBS wanted me to try it, and there was no conversation that this couldn't be done. It depends what level Silque you are getting, I suspect. My bike was built to order (SSL level); it did cost a lot more than the price you are quoting, but I think that you can probably still get this, no matter what. Work with your LBS, not Trek directly.
2015 Trek Silque SSL
Specialized Oura
2011 Guru Praemio
Specialized Oura
2017 Specialized Ariel Sport