I read an article about the physiology of adapting to heat. It involves an increase in your blood volume-- to compensate for the blood being shunted to the periphery which is part of the cooling mechanism. In very athletic people it's a matter of days, otherwise it can be weeks.
Loading up on the water might do more harm because you dilute sodium & potassium. I don't know if shot blocks have potassium and might not have enough sodium for the rides you are doing.
I was very upset Monday night. After 60-80 miles a day for Bike Across Kansas, I came home and tried to do a one-hour evening ride. I nearly throw up. We didn't actually have much heat last week in Kansas, oddly enough.
2009 Trek 7.2FX WSD, brooks Champion Flyer S, commuter bike