ALWAYS pump your tires up before you go out for a ride. Since we don't know what kind of bike you have, it's hard to give advice as to how much air to put in. However, if you look on the side of your tires you will find the maximum pressure for which you can inflate the tire.
Cleaning your chain is probably the most important thing you can do to help keep your drive train running smoothly. I generally wipe my chain after long rides and lubricate it after 100 miles. If you are using oil, let it soak in and then wipe it (and the bike frame below) before you ride again.
Be sure your LBS checks your chain for wear every few months as well. You might ask them if they measured your chain when you took it in last month. Chains stretch over time and need to be replaced when they reach a certain point on the chain gauge.
When you wipe down the bike, be sure you get under the seat tube (the bottom bracket area) and get out any dirt or sports drink that might be in that area. I have my bikes on racks in the garage so it's easy to get under them. I use Bikewash as it will clean off any dirt and sticky stuff. Be sure you get the cables clean there as well. It only takes a minute, but you'll be glad you did! Nothing like a stuck cable when you are trying to shift (it's happened to me a couple of times which is why I mention it here!)
You can wash your bike on occasion- just don't jet wash it! If you have a way to put it up on a stand, it will be easier as you can get under the frame. When you clean your wheels just check each spoke as you wash it and make sure they are tight. After washing be sure to lube your chain. Some people run their chains through a chain wash. I do that occasionally but find it's not necessary every time I clean my bike.
Hope this helps. Every time you ride, even if you do just a bit of maintenance and keep your bike clean, you'll have many years of maintenance free riding.



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Nancy
I used Simple Green to clean the bike once. Forgot what the chain cleaner I got is called, I picked it up after someone at REI told me it's good stuff.
