Are you putting a single cassette cog on a freehub? You should have the flexibility to arrange spacers on either side of the cog and select your chainline pretty well. To use the center chainring of a triple, you'll need the cog on the middle to outer 1/2 of the freehub. This sounds like a cool project. Have fun.
Oil is good, grease is better.
2007 Peter Mooney w/S&S couplers/Terry Butterfly
1993 Bridgestone MB-3/Avocet O2 Air 40W
1980 Columbus Frame with 1970 Campy parts
1954 Raleigh 3-speed/Brooks B72