I did 3 of my centuries in the middle of summer in temps between 90-100. I think one of them the temp even reached 109. (sorry I don't know the conversion to celsius) I wear a 100 oz camel back and carry 4 20 oz bottles of water, 2 in the pack and 2 on the bike with eletrolyte replacement in them. Now granted the humidity here in New Mexico stays very low in the summer so I don't have to deal with damp, sticky heat. Every time I stopped I filled up anything that was empty just to make sure I had plenty of water. I also made sure I drank at least 1 bottle per hour, sometimes more but never less.
ps: I love riding in the heat so I may not be the right person to answer this question!
Life should NOT be a journey to the grave with the intention of arriving safely in an attractive and well preserved body, but rather to skid in sideways, champagne in one hand, strawberries in the other, body thoroughly used up, totally worn out and screaming: "Yeah Baby! What a Ride!"