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Taking chain off...
The best way to take a chain off is to use a chain with a master link. That way you don't have to worry about the pins being in the right place. (We had a friend who shall remain nameless who had to miss part of the Davis double because the pin came out of his chain - which he had just replaced - presumably because it hadn't been put in all the way and he hadn't test ridden the bike til the morning of the double!)
Chains with a master link are not much more expensive than other chains and well worth it. The easier it is to properly care for your chain the longer that chain should last....
I use a Wipperman: http://www.connexchain.com/
You can also just buy the master link by itself, apparently.
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Simple Green has a foaming degreaser which I LOVE!!! It's so much easier than the spray, I use less, and it's not nearly as messy (dripping, etc.). I use my little brush for the cassette and chain, but the degreaser doesn't splat all over like it did when I used the spray bottle. No more black dots all over my white tees!!!!